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Beilstein J. Org. Chem. 2008, 4, No. 37, doi:10.3762/bjoc.4.37
Graphical Abstract
Scheme 1: Tautomerization of 1,4-dihydroxynaphthalene.
Scheme 2: Alternative routes of access to tetralin-1,4-dione.
Scheme 3: Proposed origin of diastereomeric preference in the reduction of 2.
Scheme 4: Enantioselective reduction of 2.
Scheme 5: Mono-reduction of 2.
Scheme 6: Enantioselective mono-reduction of 2.